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.Management Sciences
Category: Chemical Reaction
Half-life period for a first order reaction is _____________ the initial concentration of the reactant?
A. Directly proportional to
B. Inversely proportional to
C. Independent of
D. None of these
The energy of activation of a chemical reaction ?
A. Is same as heat of reaction at constant pressure
B. Is the minimum energy which the molecules must have before the reaction can take place
C. Varies as fifth power of the temperature
D. Both B. and C.
For a heterogeneous catalytic reaction____________________?
A. Free energy of activation is lowered in the presence of catalyst, which remains unchanged at
the end of reaction
B. A relatively small amount of catalyst can cause the conversion of large amount of reactants
which does not mean that catalyst concentration is important
C. The catalyst does not form an intermediate complex with the reactant
D. The surface of the catalyst does not play an important role during reaction
The rate constant of a reaction is a function of the ___________________?
A. Time of reaction
B. Temperature of the system
C. Extent of reaction
D. Initial concentration of the reactants
Half life period of a chemical reaction is_________________?
A. The time required to reduce the concentration of the reacting substance to half its initial value
B. Half of the space time of a reaction
C. Half of the residence time of a reaction
D. None of these
For a first order chemical reaction, the rate constant_________________?
A. Changes on changing the concentration units
B. Is not a function of the unit of time
C. Has unit of time-1
D. None of these
If ΔG (free energy change) for a chemical reaction is very large and negative, then the reaction is_______________________?
A. Not feasible
B. Just feasible
C. Very much feasible
D. Unpredictable as ΔG is no measure of feasibility of a reaction
A first order homogeneous reaction of the type X → Y → Z (consecutive reaction) is carried out in a CSTR. Which of the following curves respectively show the variation of the concentration of X, Y and Z with time ?
A. I, II, III
B. III, II, I
C. III, I, II
D. II, III, I
Effective diffusivity (DE) in a catalyst pellet is related to molecular diffusivity (DN) and Knudsen diffusivity (DK) as_________________?
A. DE = DM + DK
B. 1/DE = 1/DN + DK
C. DE = DM . DE
D. DE = DN/DE
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