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.Management Sciences
Category: Chemical Reaction
If n = overall order of a chemical reaction. a = initial concentration of reactant. t = time required to complete a definite fraction of the reaction. Then pick out the correct relationship ?
A. t ∝ 1/an
B. t ∝ 1/an – 1
C. t ∝ 1/an + 1
D. t ∝ an
For the non-catalytic reaction of particles with surrounding fluid, the time needed to achieve the same fractional conversion for particles of different but unchanging sizes is proportional to the square of particle diameter, when the _______________ is the controlling resistance?
A. Film diffusion
B. Diffusion through ash layer
C. Chemical reaction
D. Either A., B. or C.
If helium is introduced in a reactor containing O2, SO2 and SO3 at equilibrium, so that total pressure increases while volume and temperature remains constant. In this case the dissociation of SO3 (as per Le Chatelier’s principle)?
A. Decreases
B. Increases
C. Remains unaltered
D. Changes unpredictably
A catalyst inhibitor____________________?
A. Lessens its selectivity
B. May be useful for suppressing undesirable side reactions
C. Is added in small quantity during the catalyst manufacture itself
D. All A., B. and C.
Which of the following is a controlling factor in very fast heterogeneous reaction ?
A. Heat and mass transfer effects
B. Pressure
C. Temperature
D. Composition of reactant
The first order gas phase reaction as shown in the bellow figure is conducted isothermally in batch mode. The rate of change of conversion with time is given by________________?
A. dXA/dt = k1 (1 – XA)2 (1 + 2XA)
B. dXA/dt = k1 (1 – XA) (1 + 0.5XA)
C. dXA/dt = k1 (1 – XA)
D. dXA/dt = k1 (1 – XA)/(1 + XA)
The experimentally determined overall order of the reaction, A + B → C + D, is two. Then the__________________?
A. Reaction is elementary with a molecularity of 2
B. Molecularity of the reaction is 2, but the reaction may not be elementary
C. Reaction may be elementary with molecularity of 2
D. Reaction is elementary but the molecularity may not be 2
Mean residence time is equal to the space time, when_________________?
A. The feed rate is measured at temperature and pressure in the reactor
B. The temperature, pressure and the density of reaction mixture remains constant throughout the
reactor
C. There is no change in number of moles in gaseous reaction
D. All A., B. and C.
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