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.Management Sciences
Category: Chemical Reaction
When the reaction is dominated by intraparticle diffusion, the apparent order of reaction (nD) as measured is related to the true order (n) as ________________?
A. nD = (n + 1)/2
B. nD = n/2
C. nD = n + 1
D. None of these
In solid catalysed reactions the diffusional effects are more likely to affect the overall rate of reaction for________________?
A. Fast reactions in catalyst of small pore diameter
B. Fast reaction in catalyst of large pore diameter
C. Slow reactions in catalyst of small pore diameter
D. Slow reactions in catalyst of large pore diameter
Pick out the correct statement?
A. A lower temperature favours the reaction of lower activation energy
B. The dispersion number for a reactor/vessel is uL/D
C. The rate controlling step in a reaction involving many steps is the fastest step
D. Pore volume and porosity of a catalyst is measured by Brunauer-Emmett-Teller (BET)
technique
Pick out the wrong statement?
A. Catalytic activity of enzyme catalysed reactions which is affected by temperature, pH value &
chemical agents, is maximum at a temperature of about 45°C
B. Most of the enzyme catalysed reactions involve at least two substrates
C. Enzymes help in increasing the activation energy of the reaction
D. Equilibrium concentrations in enzyme catalysed reactions can be calculated by using the
thermodynamic properties of substrates & products
A rise in temperature ______________________?
A. Normally tends to increase the reaction rate
B. Does not affect a catalysed reaction
C. Does not affect photo-chemical reaction rates
D. All A., B. and C.
The rate equation for the reaction represented by as shown in the bellow figure, is given by – rx = K1 . Cx/(1 + K2 Cx). At high value of Cx (i.e.., K2Cx > > 1), the order of the reaction and the rate constant are respectively___________________?
A. Zero order & K1/K2
B. Zero order & K1
C. First order & K1
D. First order & K1/K2
______________ is the response curve for a step input signal from a reactor ?
A. S-curve
B. C-curve
C. I-curve
D. None of these
The preferred reacting system for oxidation of o-xylene to phthalic anhydride is _____________________?
A. Jacketed liquid phase CSTR
B. Jacketed steam heated multitubular reactor
C. Multitubular reactor with cooling
D. Multistage multitubular reactor with interstage cooling
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