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.Management Sciences
Category: Chemical Reaction
Pick out the wrong statement ?
A. For the same conversion, the holding time required in a batch reactor, is always equal to the space time required in a PFR
B. Two mixed reactors of unequal size are available for producing a specified product, formed by
a homogenous second order reaction. To achieve maximum production rate, the smaller
reactor should be placed in series before the larger reactor
C. Arrhenius equation describing the effect of temperature on rate constant is given by,
K = A.e-Ea/RT
D. The mechanism for the decomposition of CH3CHO into CH4 and CO in presence of I2 is:
CH3CHO + I2 → CH3I + HI + CO; slow
CH3I + HI → CH4 + I2; fast
Then the rate of disappearance of CH3CHO is equal to K.CCH3I.CHI and acts as a catalyst
A stirred tank reactor compared to tubular-flow reactor provides____________________?
A. More uniform operating conditions
B. Permits operation at the optimum temperature for a long reaction time
C. Higher overall selectivity for a first order consecutive reaction
D. All A., B. and C.
In an ideal P.F.R. at steady state conditions ___________________?
A. The composition of reactants remains constant along a flow path
B. The conversion of the reactant varies from point to point along a flow path
C. There is no lateral mixing of fluid
D. There may be diffusion along the flow path
In case of a/an ______________ chemical reaction, conversion increases with the rise in temperature?
A. Reversible exothermic
B. Irreversible exothermic
C. Irreversible endothermic
D. Reversible endothermic
Pick out the correct statement?
A. In catalytic reactions, the catalyst reacts with the reactants
B. A catalyst initiates a chemical reaction
C. A catalyst lowers the activation energy of the reacting molecules
D. A catalyst cannot be recovered chemically unchanged at the end of the chemical reaction
Transition state theory relates the above quantities as___________________?
A. k ∝ e-E/RT
B. k ∝ T.eE/RT
C. k ∝ √T
D. k ∝ T1.5
An imbalanced chemical reaction equation is against the law of________________?
A. Multiple proportion
B. Conservation of mass
C. Constant proportion
D. None of these
With increase in initial concentration, the fractional conversion of a first order reaction in a given time___________________?
A. Increases
B. Decreases
C. Remain constant
D. Unpredictable
Semibatch reactor is preferred, when a/an__________________?
A. A highly exothermic reaction is to be controlled
B. Undesirable side reaction (at high concentration of one of the reactants) is to be avoided
C. A gas is to be reacted with liquid (e.g. hydrogenation of fat)
D. All A., B., and C.
An exothermic reaction takes place in an adiabatic reactor. The product temperature ______________ reactor feed temperature?
A. Is always equal to
B. Is always greater than
C. Is always less than
D. May be greater or less than
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