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.Management Sciences
Category: Thermodynamics for Chemical
Pick out the wrong statement ?
A. Minimum number of degree of freedom of a system is zero
B. Degree of freedom of a system containing a gaseous mixture of helium, carbon dioxide and
hydrogen is 4
C. For a two phase system in equilibrium made up of four non-reacting chemical species, the
number of degrees of freedom is 4
D. Enthalpy and internal energy change is zero during phase change processes like melting,
vaporisation and sublimation
Vapour which is at a pressure smaller than the saturation pressure for the temperature involved is called a _____________ vapour?
A. Superheated
B. Desuperheated
C. Non-condensable
D. None of these
Free energy change at equilibrium is____________________?
A. Zero
B. Positive
C. Negative
D. Indeterminate
The equation, PV = nRT, is best obeyed by gases at____________________?
A. Low pressure & high temperature
B. High pressure & low temperature
C. Low pressure & low temperature
D. None of these
The necessary condition for phase equilibrium in a multiphase system of N components is that the____________________?
A. Chemical potentials of a given component should be equal in all phases
B. Chemical potentials of all components should be same in a particular phase
C. Sum of the chemical potentials of any given component in all the phases should be the same
D. None of these
At constant temperature and pressure, for one mole of a pure substance, the ratio of the free energy to the chemical potential is____________________?
A. Zero
B. One
C. Infinity
D. Negative
Which of the following has the minimum value of COP for a given refrigeration effect ?
A. Reverse Carnot cycle
B. Ordinary vapour-compression cycle
C. Vapour-compression process with a reversible expansion engine
D. Air refrigeration cycle
In the reaction, C + O2 → CO2; ΔH = – 94 kcal. What is the heat content (enthalpy) of O2 ?
A. -94 kcal
B. > -94 kcal
C. < – 94 kcal
D. Zero
Out of the following refrigeration cycles, which one has maximum COP ?
A. Air cycle
B. Carnot cycle
C. Ordinary vapor compression cycle
D. Vapor compression with a reversible expansion engine
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